Acid-Base Equilibria in Organic Chemistry.

Basic principles of electrolyte chemistry for microfluidic electrokinetics. Part I: Acid-base equilibria and pH buffers.

We review fundamental and applied acid-base equilibrium chemistry useful to microfluidic electrokinetics. We present elements of acid-base equilibrium reactions and derive rules for pH calculation for simple buffers. We also present a general formulation to calculate pH of more complex, arbitrary mixtures of electrolytes, and discuss the effects of ionic strength and temperature on pH calculati...

The ABC of Acid-base Chemistry

This book is a collection of abstracts of the world literature in surgery written by the abstract and news editor of the Journal of the International College of Surgeons. The volume is attractive in format and is easy to use. Complete references are listed at the end of each abstracted article, most of which were published in 1949. The papers were chosen on the basis of the unusual, the interes...

QuantItatIve acId - Base chemIstry and PhysIology

Definitions and terminology in blood acid-base chemistry.

1. Should Brfinsted-Lowry's acid-base definitions be adopted or should the term acid-base balance be synonymous with the term electrolyte balance? 2. Are the relevant parameters pH, Pcoz and actual bicarbonate, or is it preferable to have a more direct measure for the accumulation of nonvolatile acid or base than the bicarbonate value, such as, for instance, standard bicarbonate, buffer base, o...

Basic principles of electrolyte chemistry for microfluidic electrokinetics. Part II: Coupling between ion mobility, electrolysis, and acid-base equilibria.

We present elements of electrolyte dynamics and electrochemistry relevant to microfluidic electrokinetics experiments. In Part I of this two-paper series, we presented a review and introduction to the fundamentals of acid-base chemistry. Here, we first summarize the coupling between acid-base equilibrium chemistry and electrophoretic mobilities of electrolytes, at both infinite and finite dilut...